Publications by Dr Keith Izod - ePrints

Browsing publications by Dr Keith Izod.

Newcastle Authors	Title	Year
Ahmed Alwaaly Dr Casey Dixon Dr Paul Waddell Professor William Clegg Professor Mike Probert et al.	Alkali Metal Complexes of Phosphine-Borane-Substituted Benzyl Ligands and Their Application in the Synthesis of B-H···Sn Stabilized Dialkylstannylenes	2024
Dr Keith Izod Dr Paul Waddell	Phosphido-borane-supported stannates	2023
Dr Mo Liu Dr Ahmed Alwaaly Dr Paul Waddell Dr Keith Izod	Revisiting the Schlenk Dimerisation Reaction of 1,1-Diphenylethene	2023
Dr Keith Izod Dr Mo Liu Dr Peter Evans Dr Corinne Wills Dr Casey Dixon et al.	Spontaneous Decomposition of an Extraordinarily Twisted and Trans-Bent Fully-Phosphanyl-Substituted Digermene to an Unusual Ge^I Cluster	2022
Dr Keith Izod Dr Paul Waddell	Substituent Effects on the Structures of Alkali Metal Phosphido-Borane Complexes	2022
Dr Keith Izod James Watson Dr Ross Harrington Professor William Clegg	Phosphido-bis(borane) complexes of the alkaline earth metals	2021
Dr Keith Izod Dr Paul Waddell	P-Ge/Sn π-Interactions Versus Arene^…Ge/Sn Contacts for the Stabilization of Diphosphatetrylenes, (R₂P)₂E (E = Ge, Sn)	2020
Dr Keith Izod Dr Peter Evans Dr Paul Waddell	An Acyclic Arsenium Cation Stabilised by a Single P‐As π‐Interaction and a Cyclic Diphosphinophosphonium Salt	2019
Dr Keith Izod Dr Paul Waddell	Unexpected Activation of Ethers and Polysiloxanes by a Phosphine-Borane-Stabilized 1,3-Dicarbanion/Butyllithium Couple	2019
Dr Keith Izod Dr Peter Evans Dr Paul Waddell	A diarsagermylene and a diarsastannylene stabilised by arene⋯Ge/Sn interactions	2018
Dr Keith Izod Dr Peter Evans Emeritus Professor William McFarlane Dr Paul Waddell	Influence of Chain Length on the Structures and Dynamic Behavior of Alkyl-Tethered alpha,omega-Diphosphide Complexes of Lithium and Their Use in the Synthesis of P-Heterocyclic Stannylenes	2018
Dr Keith Izod Dr Peter Evans Dr Paul Waddell	A Fully Phosphane-Substituted Disilene	2017
Dr Keith Izod Claire Jones Dr Ross Harrington Dr Paul Waddell	A Suite of Sterically-Demanding Hybrid Alkyl/Cyclopentadienyl Ligands	2017
Dr Keith Izod James Watson Salima El-Hamruni Dr Ross Harrington Dr Paul Waddell et al.	Alkali-metal- and alkaline-earth-metal-mediated C-O activation of an anisole-substituted phosphido-borane ligand	2017
Dr Keith Izod Dr Peter Evans Dr Paul Waddell	Desolvation and Aggregation of Sterically Demanding Alkali Metal Diarylphosphides	2017
Dr Keith Izod Dr Peter Evans Dr Paul Waddell Professor Mike Probert	Remote Substituent Effects on the Structures and Stabilities of P=E π-Stabilized Diphosphatetrylenes (R₂P)₂E (E = Ge, Sn)	2016
Dr Keith Izod Dr Paul Waddell	Dibenzylstrontium and -barium: Simple Molecules with Complex Structures	2015
Dr Keith Izod Dr Casey Dixon Dr Ross Harrington Professor Mike Probert	Impact of a rigid backbone on the structure of an agostically-stabilised dialkylstannylene: isolation of an unusual bridged stannyl–stannylene	2015
Dr Keith Izod Dr Corinne Wills Salima El-Hamruni Dr Ross Harrington Dr Paul Waddell et al.	Structural Diversity in Alkaline Earth Metal Complexes of a Phosphine-Borane-Stabilized 1,3-Dicarbanion	2015
Dr Keith Izod Dr Corinne Wills Dr Ross Harrington Professor Mike Probert	Insights into the stability and structures of phosphine-boranes and their α-metalated derivatives	2014
Dr Keith Izod Salima El-Hamruni Dr Ross Harrington Dr Ulrich Baisch	Stabilization of a Diphosphagermylene through pπ-pπ Interactions with a Trigonal-Planar Phosphorus Center	2014
Dr Keith Izod Dr Casey Dixon Dr Ross Harrington Dr Ulrich Baisch	Synthesis and Structural Characterization of Phosphine-Borane-Stabilized Dicarbanions with either Rigid or Flexible Spacers	2014
Dr Keith Izod Dr Corinne Wills Professor Mike Probert Dr Ross Harrington	Synthesis and structure of an acyclic dialkylstannylene	2014
Dr Keith Izod Dr Ewan Clark Professor William Clegg Dr Ross Harrington	Light-Induced Rearrangement of Thioether-Substituted Phosphanide Ligands: Scope and Limitations of a Remarkable Isomerization	2013
Dr Keith Izod James Watson Professor William Clegg Dr Ross Harrington	Phosphido-Borane and Phosphido-Bis(Borane) Complexes of the Alkali Metals, a Comparative Study	2013
Dr Keith Izod Dr Corinne Wills Dr Ross Harrington Professor William Clegg	Synthesis and structural characterisation of an unusual phosphine-borane-substituted organoplumbate	2013
Dr Keith Izod James Watson Professor William Clegg Dr Ross Harrington	Benzyl Ether-Substituted Phosphido-Borane Complexes of the Alkali Metals	2012
Dr Keith Izod	Heavier group 14 complexes with anionic P-donor ligands	2012
Dr Keith Izod Dr Ewan Clark Professor William Clegg Dr Ross Harrington	Hypervalent Sulfur-Functionalized Diphosphagermylene and Diphosphastannylene Compounds	2012
Dr Keith Izod Dr Corinne Wills Dr Ross Harrington Professor William Clegg	Agostically-stabilized dialkylstannylenes and plumbylenes	2011
Dr Keith Izod Dr Ewan Clark John Stewart	Edge- versus Vertex-Inversion at Trigonal Pyramidal Ge(II) Centers—A New Aromatic Anchimerically Assisted Edge-Inversion Mechanism	2011
Dr Keith Izod Julia Watson Professor William Clegg Dr Ross Harrington	Synthesis, structures and stabilities of thioanisole-functionalised phosphido-borane complexes of the alkali metals	2011
Dr Keith Izod John Stewart Dr Ewan Clark Professor William Clegg Dr Ross Harrington et al.	Germanium(II) and Tin(II) Complexes of a Sterically Demanding Phosphanide Ligand	2010
Dr Keith Izod Professor William Clegg Dr Ross Harrington	Lanthanide(II) complexes of a phosphine-borane-stabilised carbanion	2010
Dr Corinne Wills Dr Keith Izod Professor William Clegg Dr Ross Harrington	Oxidation reactions of a phosphine-borane-stabilised dialkylstannylene	2010
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Synthesis, Structure, and Solution Behavior of a Phosphine-Borane-Stabilized 1,3-Dicarbanion	2010
Dr Keith Izod John Stewart Professor William Clegg Dr Ross Harrington	Synthesis, structures and dynamic behavior of intramolecularly base-stabilized diphosphatetrylenes containing a five-membered chelate ring	2010
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Acyclic Dialkylstannylene and -Plumbylene Compounds That Are Monomeric in the Solid State	2009
Dr Keith Izod Dr Ewan Clark Emeritus Professor William McFarlane Dr Ben Allen Professor William Clegg et al.	Dynamic Behavior of Intramolecularly Base-Stabilized Phosphatetrylenes. Insights into the Inversion Processes of Trigonal Pyramidal Geramanium(II) and Tin(II) Centers	2009
Dr Corinne Wills Dr Keith Izod Jonathan Young Professor William Clegg Dr Ross Harrington et al.	Mixed donor-functionalised phosphinomethanide complexes of the alkali metals; synthesis, structures, and solution dynamics	2009
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B-H center dot center dot center dot E Interactions [E = Sn, Pb]	2009
Dr Keith Izod Lyndsey Bowman Dr Corinne Wills Professor William Clegg Dr Ross Harrington et al.	Synthesis and structural characterisation of alkali metal complexes of heteroatom-stabilised 1,4-and 1,6-dicarbanions	2009
Dr Keith Izod Emeritus Professor William McFarlane Dr Corinne Wills Professor William Clegg Dr Ross Harrington et al.	Agostic-type B - H⋯Pb interactions stabilize a dialkylplumbylene. Structure of and bonding in [{nPr2P(BH3)}(Me 3Si)C(CH2)]2Pb	2008
Dr Keith Izod John Stewart Professor William Clegg Dr Ross Harrington	Alkali metal complexes of a naphthylamine-substituted phosphanide	2008
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Alkali metal complexes of a phosphine-borane-stabilised carbanion: Influence of co-ligands on structure	2007
Dr Keith Izod John Stewart Professor William Clegg Dr Ross Harrington	Alkali metal complexes of sterically demanding amino-functionalised secondary phosphanide ligands	2007
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Alkaline earth metal complexes of a phosphine-borane-stabilized carbanion: Synthesis, structures, and stabilities	2007
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Influence of aromatic ring substituents and co-ligand on the binding mode of a phosphine-borane-stabilized carbanion; crystal structures of [[(Me3Si)2{Ph2P(BH3)}C]KLn]2[Ln = (OEt2)2, pmdeta; pmdeta = N,N,N′,N″,N″-pentamethyldiethylenetriamine]	2007
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Metalation of trimethylphosphine-borane. Unexpected reactivity of a simple phosphine-borane-stabilized carbanion toward siloxanes	2007
Dr Keith Izod Professor William Clegg Dr Ross Harrington	Synthesis and structures of Ln(II) and Ln(III) dialkyls derived from LnI2 (Ln = Nd, Tm, Yb)	2007
Dr Keith Izod Professor William Clegg Dr Ross Harrington	σ-Bonded organometallic derivatives of yttrium(III) and thulium(III): An unusual ligand coupling reaction mediated by thulium(III)	2007
Dr Keith Izod Professor William Clegg Dr Ross Harrington	Alkali metal complexes of sterically hindered mono- and di-carbanions containing Si-O bonds	2006
Dr Keith Izod Dr Stephen Liddle Professor William Clegg Dr Ross Harrington	Amino-functionalised diarylphosphide complexes of the alkali metals and lanthanum	2006
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Heavier alkali metal complexes of a silicon- and phosphine-borane- stabilized carbanion	2006
Lyndsey Bowman Dr Keith Izod Professor William Clegg Dr Ross Harrington	Heteroleptic complexes of lanthanum(III) and neodymium(III) with oxygen- or nitrogen-functionalized tris(triorganosilyl)methyl ligands	2006
Dr Keith Izod Emeritus Professor William McFarlane Brent Tyson Professor William Clegg Dr Ross Harrington et al.	Stabilization of a dialkylstannylene by unusual B-H⋯Sn γ-agostic-type interactions. A structural, spectroscopic, and DFT study	2006
Dr Stephen Liddle Dr Keith Izod	Synthesis and crystal structure of the heteroleptic lanthanum(III) bis-diphosphinomethanide complex [La{CH(PPh2)2}2(I)(THF)2]	2006
Dr Keith Izod Dr Corinne Wills Professor William Clegg Dr Ross Harrington	Synthesis, crystal structure, and solution behavior of a sterically hindered α-metalated phosphine-borane	2006
Dr Keith Izod Emeritus Professor William McFarlane Dr Ben Allen Professor William Clegg Dr Ross Harrington et al.	An intramolecularly base-stabilized diphosphagermylene and two unusual germanium(II) ate complexes: A structural, NMR, and DFT study	2005
Dr Keith Izod Jonathan Young Professor William Clegg Dr Ross Harrington	Effect of peripheral donor substituents on the binding modes of phosphinomethanide ligands. Synthesis and crystal structures of alkali metal derivatives of an O-functionalised phosphinomethanide ligand	2005
Dr Keith Izod	The germanium(II) ate complex [Ph3PiPr][Ge(OCOMe) 3]: The first structurally characterized compound containing a discrete [E14(II)O3](-) (E14(II) = Si, Ge, Sn or Pb) anion	2005
Dr Keith Izod Dr Stephen Liddle Professor William Clegg	A Convenient Route to Lanthanide Triiodide THF Solvates. Crystal Structures of Lnl3(THF)4 [Ln = Pr] and Lnl 3(THF)3.5 [Ln = Nd, Gd, Y]	2004
Dr Keith Izod Emeritus Professor William McFarlane Brent Tyson Professor William Clegg Dr Ross Harrington et al.	Complexes of a dianionic bis(diphosphinomethanide) with lithium, sodium, potassium and zirconium. Effect of substitution on the Schlenk dimerisation of vinylidene phosphines	2004
Stuart Blair Dr Keith Izod Professor William Clegg Dr Ross Harrington	Complexes of the heavier alkaline earth metals Ca, Sr, and Ba with O-functionalized phosphanide ligands	2004
Dr Keith Izod Dr Stephen Liddle Professor William Clegg	Protonation of a lanthanum phosphide-alkyl occurs at the P-La not the C-La bond: Isolation of a cationic lanthanum alkyl complex	2004
Dr Keith Izod Emeritus Professor William McFarlane Brent Tyson	Scope and limitations of the Peterson olefination reaction as a route to vinylidene phosphanes	2004
Dr Stephen Liddle Dr Keith Izod	Synthesis and characterization of 1,3-diphosphapropene and alkali-metal 1,3-diphosphaallyl complexes and unexpected 1,3-rearrangement of a cesium 1,3-diphosphaallyl complex to a cesium secondary phosphanide	2004
Dr Keith Izod Dr Stephen Liddle Emeritus Professor William McFarlane Professor William Clegg	Synthesis and reactions of sterically encumbered, heteroleptic lanthanum phosphides. Structural characterization of [{(Me₃Si)₂CH}-(C₆H₄-2-Ch₂NMe ₂)P]₂La(OR) and [{(Me₃Si)₂CH}- (C₆)H₄-2-CH₂NMe₂)P]La(THF)[P(C₆H₄-2-CH₂NMe₂)-{CH(SiMe ₃)(SiMe₂CH₂)}] [R =i-Pr, t-Bu]	2004
Dr Keith Izod Dr Stephen Liddle Emeritus Professor William McFarlane Professor William Clegg	Synthesis and Reactions of Sterically Encumbered, Heteroleptic Lanthanum Phosphides. Structural Characterization of [{(Me₃Si)₂CH}-(C₆H₄-2-CH₂NMe₂)P]₂La(OR) and [{(Me₃Si)₂CH}- (C₆H₄-2-CH₂NMe₂)P]La(THF)[P(C₆H₄-2-CH₂NMe₂)-{CH(SiMe₃)(SiMe₂CH₂)}] [R = i-Pr, t-Bu]	2004
Dr Keith Izod Emeritus Professor William McFarlane Brent Tyson Professor William Clegg Dr Ross Harrington et al.	Synthesis and structural characterisation of a novel phosphine-borane- stabilised dicarbanion and an unusual bis(phosphine-borane)	2004
Dr Keith Izod Emeritus Professor William McFarlane Brent Tyson Professor William Clegg Dr Ross Harrington et al.	Alkali Metal-Mediated Schlenk Dimerization of a Phosphorus-Substituted Alkene. Synthesis and Crystal Structures of Li, Na, and K Derivatives of a Phosphorus-Stabilized Butane-l,4-diide Ligand	2003
Dr Keith Izod Dr Stephen Liddle Professor William Clegg	Alkyl complexes of strontium and barium: Synthesis and structural characterization of {(Me3Si)2(MeOMe2Si)C}2Sr(THF) and {(Me3Si)2(MeOMe2Si)C}2Ba (MeOCH2CH2OMe)	2003
Dr Keith Izod Professor William Clegg	C2-Symmetric ytterbium(II) complexes with a novel, chiral P,N-donor ligand	2003
Dr Keith Izod Professor William Clegg Dr Ross Harrington	Organomagnesium phosphanide "grignard" analogues - Synthesis, structural characterisation and solution behaviour of [BuMg{P(CH[SiMe 3]2)(C6H3-2-OMe-3R)}]2 [R = H, Me]	2003
Dr Keith Izod Dr Ross Harrington Professor William Clegg	Sterically controlled mono- or dimetalation of a thioether-functionalized phosphine and an unusual light-induced phosphide-thiolate rearrangement	2003
Dr Stephen Liddle Dr Keith Izod	The first structurally authenticated alkali metal 1,3-diphosphaallyl complex [{ButC(PMes)2}Li(thf)3] (Mes = 2,4,6-Me3C6H2): An alternative synthetic approach to substituted 1,3-diphosphaallyl complexes	2003
Stuart Blair Dr Keith Izod Professor William Clegg	A homologous series of alkaline earth phosphanides: Syntheses, crystal structures, and unusual dynamic behavior of (THF),nM[P{CH(Si-Me3)2} (C6H4-2-CH2NMe2)]2 (M = Mg, Ca, Sr, Ba)	2002
Dr Keith Izod Professor William Clegg	A Homologous Series of Alkaline Earth Phosphanides: Syntheses, Crystal Structures, and Unusual Dynamic Behavior of (THF)_nM[P{CH(Si- Me₃)₂}(C₆H₄-2-CH₂NMe₂)]₂ (M = Mg, Ca, Sr, Ba)	2002
Dr Keith Izod	A new era in divalent organolanthanide chemistry?	2002
Dr Keith Izod	A new era in divalent organolanthanide chemistry?	2002
Dr Keith Izod	Complexes of P-stabilised carbanions with s- and p-elements	2002
Dr Keith Izod Emeritus Professor William McFarlane Professor William Clegg	Dilithio-1,1,2-tris(diphenylphosphinoyl)ethane-1,2-diide: The first formal 1,2-dicarbanion stabilised by phosphorus?	2002
Dr Keith Izod Professor William Clegg	Isolation and structural characterisation of two sterically crowded diphosphanes	2002
Dr Keith Izod Paul O'Shaughnessy Professor William Clegg	Unusual solvent-promoted smiles rearrangement of two different phosphorus-containing organolithium compounds to the same lithium phosphide. Crystal structure of MeP{C6H4-2-CH(C6H4-2-CH2N Me2)NMe2}Li(THF)2	2002
Dr Keith Izod Paul O'Shaughnessy Professor William Clegg Dr Stephen Liddle	Regioselective metalation of a tertiary phosphine. Synthesis and structural characterization of an unusual tetramerie lithium phosphinomethanide	2001
Dr Keith Izod Professor William Clegg Dr Stephen Liddle	The first structurally authenticated Rb-PR3 and Cs-PR3 contacts. Synthesis and crystal structures of [Rb{(Me3Si)2CP(C6H4-2-CH2 NMe2)2}]n and [Cs{(Me3Si)2CP(C6H4-2-CH2 NMe2)2}(toluene)]n	2001
Dr Keith Izod	Group I complexes of P- and as-donor ligands	2000
Professor William Clegg Dr Keith Izod Paul O'Shaughnessy	Manganese and cesium derivatives of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH 2Me2Si(Me3Si)2C. Crystal structures of Li(THF)2.75(Et2O)0.25(μ-Cl)-MnC(SiMe 3)2SiMe2CH2CH2Me 2Si(Me3Si)2C	2000
Professor William Clegg Dr Keith Izod Paul O'Shaughnessy	Manganese and Cesium Derivatives of the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal Structures of Li(THF)2.75(Et2O)0.25(μ-Cl)- MnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C and (C6H6)3CsC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CCs(C6H6)3	2000
Dr Keith Izod Professor William Clegg Dr Stephen Liddle	Parallels between the chemistry of alkoxo-phosphidecalcium(II) and ytterbium(II). Synthesis and crystal structure of a calcium alkoxo-phosphide cuboidal complex	2000
Professor William Clegg Dr Keith Izod Dr Stephen Liddle	Synthesis and crystal structure of a homoleptic, alkali metal-free lanthanide(II) phosphide complex	2000
Dr Keith Izod Paul O'Shaughnessy Dr Joanne Sheffield Professor William Clegg Dr Stephen Liddle et al.	Synthesis and structural characterization of Sm(II) and Yb(II) complexes containing sterically demanding, chelating secondary phosphide ligands	2000
Professor William Clegg Dr Keith Izod Dr Stephen Liddle Paul O'Shaughnessy Dr Joanne Sheffield et al.	Synthesis and structural characterization of the first lanthanide(II) cuboidal cluster. Unexpected C-O activation by an unchanged ytterbium(II) center	2000
Dr Maurice Hill Dr Keith Izod Paul O'Shaughnessy Professor William Clegg	Synthesis, structures, and solution dynamics of functionalized phosphinomethanide complexes of the alkali metals	2000
Professor William Clegg Dr Keith Izod Paul O'Shaughnessy	First structurally authenticated heavier alkali metal phosphinomethanide	1999
Professor William Clegg Dr Simon Doherty Dr Keith Izod Paul O'Shaughnessy Dr Joanne Sheffield et al.	Monomeric alkali metal complexes of a sterically demanding, donor-functionalised secondary phosphide ligand	1999
Professor William Clegg Dr Keith Izod Emeritus Professor William McFarlane Paul O'Shaughnessy	Regioselective metalation of a tertiary phosphine. Solution and solid-state structures of an unusual aminobenzyllithium complex	1999
Professor William Clegg Dr Keith Izod Paul O'Shaughnessy	Tris(triorganosilyl)methyl derivatives of potassium and lithium bearing dimethylamino or methoxy substituents at silicon. Crystal structures of KC(SiMe3)2(SiMe2NMe2), KC(SiMe2NMe2)3 and [LiC(SiMe3)(SiMe2OMe)2]2	1999