Browse by author
Lookup NU author(s): Dr Keith Izod, Professor William Clegg, Dr Stephen Liddle
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
Metathesis between CaI2 and K[P{CH(SiMe3)2}(C6H4-2-OMe)] in THF yields the alkoxophosphide complex [Ca{P(CH[SiMe3]2)(C6H 4-2-O)}(THF)]4·4THF (2) via a ligand cleavage reaction involving the migration of a methyl group from oxygen to phosphorus. X-ray crystallography shows that 2 contains a Ca4O4 cuboidal core with μ2-phosphide groups bridging four of the faces of the cuboid. © 2000 American Chemical Society.
Author(s): Izod K, Clegg W, Liddle ST
Publication type: Article
Publication status: Published
Journal: Organometallics
Year: 2000
Volume: 19
Issue: 18
Pages: 3640-3643
ISSN (print): 0276-7333
ISSN (electronic): 1520-6041
Publisher: American Chemical Society
URL: http://dx.doi.org/10.1021/om000357b
DOI: 10.1021/om000357b
Altmetrics provided by Altmetric