Toggle Main Menu Toggle Search

Open Access padlockePrints

Synthesis, crystal structure, and solution behavior of a sterically hindered α-metalated phosphine-borane

Lookup NU author(s): Dr Keith Izod, Dr Corinne Wills, Professor William Clegg, Dr Ross Harrington

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

Treatment of the phosphine-borane adduct (Me3-Si) 2CHPMe2(BH3) (4) with n-BuLi in THF, followed by recrystallization from diethyl ether/methylcyclohexane, gives (THF) 3Li-{(Me3Si)2CPMe2(BH 3)}2Li (5), which crystallizes as a contact ion multiple ate complex. In solution 5 is subject to a dynamic equilibrium between the ate complex and a second, possibly monomeric species. © 2006 American Chemical Society.


Publication metadata

Author(s): Izod K, Wills C, Clegg W, Harrington RW

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 2006

Volume: 25

Issue: 1

Pages: 38-40

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om0509701

DOI: 10.1021/om0509701


Altmetrics

Altmetrics provided by Altmetric


Share