ePrints

Synthesis, structures, and solution dynamics of functionalized phosphinomethanide complexes of the alkali metals

Lookup NU author(s): Dr Maurice Hill, Dr Keith Izod, Paul O'Shaughnessy, Professor William Clegg

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.

Abstract

Metathesis between [Li{(Me3Si)2C}P(C6 H4-2-CH2NMe2)2] and NaOBut in ether yields the sodium phosphinomethanide [Na{(Me3Si)2C}P(C6 H4-2-CH2NMe2)2(Et2O)0.5(DME)0.5] (2b) after recrystallization. Complex 2b and its Li and K analogues are highly fluxional in solution, and the dynamic processes accounting for this have been studied by variable-temperature 1H NMR spectroscopy.

Publication metadata

Author(s): Stuart Hill MN, Izod K, O'Shaughnessy P, Clegg W

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 2000

Volume: 19

Issue: 22

Pages: 4531-4535

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om000447g

DOI: 10.1021/om000447g

Altmetrics

Share