Toggle Main Menu Toggle Search

Open Access padlockePrints

Manganese and Cesium Derivatives of the Bulky Bidentate Ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C. Crystal Structures of Li(THF)2.75(Et2O)0.25(μ-Cl)- MnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C and (C6H6)3CsC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CCs(C6H6)3

Lookup NU author(s): Professor William Clegg, Dr Keith Izod, Paul O'Shaughnessy

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

The reaction between the lithate [Li(THF)(4)]-[CH2SiMe2C(SiMe3)(2)LiC(SiMe3)(2)SiMe2CH2] and MnCl2 has given a chloride-bridged high-spin lithium manganate, isolated as Li(THF)(2.75)(Et2O)(0.25)(mu-Cl)MnC(SiMe3)(2)SiMe2CN2CH2Me2Si(Me3Si)(2)C, shown by an X-ray study to contain three-coordinate planar manganese. The ligand precursor HC(SiMe3)(2)SiMe2CH2CH2Me2Si(Me3Si)(2)CH reacts with methylcesium to give a compound isolated after recrystallization from benzene as (C6H6)(3)CsC(SiMe3)SiMe2CH2CH2Me2Si(Me3Si)(2)CCs(C6H6)(3), in which benzene solvate molecules show a variety of hapticities.


Publication metadata

Author(s): Eaborn C, Hitchcock PB, Smith JD, Zhang SB, Clegg W, Izod K, O'Shaughnessy P

Publication type: Article

Publication status: Published

Journal: Organometallics

Year: 2000

Volume: 19

Issue: 6

Pages: 1190-1193

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om991020g

DOI: 10.1021/om991020g


Altmetrics

Altmetrics provided by Altmetric


Share