Toggle Main Menu Toggle Search

Open Access padlockePrints

Niobium η-cyclopentadienyl compounds with imido and amido ligands derived from tert-butylamine

Lookup NU author(s): Professor Mike Green, Dr Mark Elsegood, Professor William Clegg

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

The niobium eta -cyclopentadienyl compounds with imido and amido ligands [Nb(eta -C5H5)((NBu)-Bu-t)((NHBu)-Bu-t)Cl] 1,* [Nb(eta -C5H5)((NBu)-Bu-t)((NHBu)-Bu-t)Bu-n] 2, [Nb(eta -C5H5)((NBu)-Bu-t)((NHBu)-Bu-t)(2)] 3, [Nb(eta -C5H5)((NBu)-Bu-t)((NHBu)-Bu-t)Me] 4, [Nb(eta -C5H5)(eta (1)-C5H5)((NBu)-Bu-t)((NHBu)-Bu-t)] 5, [Nb{(eta -C5H4)CMe2(eta (1)-C5H4)}((NBu)-Bu-t)((NHBu)-Bu-t)] 6, [Nb(eta -C5H5){N((C6H3Pr2)-Pr-i-2,6)}((NHBu)-Bu-t)Cl] 7,* [Nb(eta -C5H5){N((C6H3Pr2)-Pr-i-2,6)}((NHBu)-Bu-t)Me] 8, [Nb(eta -C5H5)((NBu)-Bu-t)(NEt2)Cl] 9 and [Nb(eta -C5H5)((NBu)-Bu-t)((NHBu)-Bu-t)(NEt2)] 10 have been prepared (* indicates the crystal structure has been determined). A correlation between the chemical shift of the NH proton and the value of Delta delta measured between the alpha and beta carbons of the tert-butyl groups of the amido ligands is discussed in relation to the degree of electron donation from the amido ligand to the niobium centre.


Publication metadata

Author(s): Humphries MJ, Green MLH, Leech MA, Gibson VC, Jolly M, Williams DN, Elsegood MRJ, Clegg W

Publication type: Article

Publication status: Published

Journal: Journal of the Chemical Society - Dalton Transactions

Year: 2000

Issue: 22

Pages: 4044-4051

Print publication date: 01/01/2000

ISSN (print): 1472-7773

ISSN (electronic): 1364-5447

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b006333i

DOI: 10.1039/b006333i


Altmetrics

Altmetrics provided by Altmetric


Share