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Lookup NU author(s): Rachel Dixon
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Desymmetrisation of a meso-imide by enantioselective reduction using a chiral oxazaborolidine catalyst derived from (1R,2S)-cis-1-amino-2-indanol followed by reduction of the hydroxylactam product proceeded with good enantiomeric excess (80-91%) at significantly lower catalyst loadings compared to reactions using the prolinol-derived catalyst. Models for the selectivity observed are proposed based upon structural probes and experimental observations. (C) 2002 Elsevier Science Ltd. All rights reserved.
Author(s): Dixon RA, Jones S
Publication type: Article
Publication status: Published
Journal: Tetrahedron: Asymmetry
Year: 2002
Volume: 13
Issue: 10
Pages: 1115-1119
ISSN (print): 0957-4166
ISSN (electronic): 1362-511X
Publisher: Pergamon
URL: http://dx.doi.org/10.1016/S0957-4166(02)00248-3
DOI: 10.1016/S0957-4166(02)00248-3
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