ePrints

Structurally Defined Reactions of Sodium TMP–Zincate with Nitrile Compounds: Synthesis of a Salt-Like Sodium Sodiumdizincate and Other Unexpected Ion-Pair Products

Lookup NU author(s): Professor William Clegg, Dr Sophie Dale, Dr Luca Russo

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.

Abstract

Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes. (Chemical Equation Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Publication metadata

Author(s): Clegg W, Dale SH, Hevia E, Hogg LM, Honeyman GW, Mulvey RE, O'Hara CT, Russo L

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie: International Edition

Year: 2008

Volume: 47

Issue: 4

Pages: 731-734

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.200704341

DOI: 10.1002/anie.200704341

Altmetrics

Share