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Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation

Lookup NU author(s): Professor William Clegg, Dr Sophie Dale

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Abstract

Benzene can be easily 1,4-dideprotonated stoichiometrically on reaction with two equivalents of a synergic mixture of tBu2Zn, NaTMP and TMEDA to give a unique 1,4-dizincated benzene product which has been characterised by X-ray crystallography and NMR spectroscopy as well as modelled theoretically by DFT computational studies; a related synergic dimagnesiation of benzene is also reported. © The Royal Society of Chemistry.

Publication metadata

Author(s): Armstrong DR, Clegg W, Dale SH, Graham DV, Hevia E, Hogg LM, Honeyman GW, Kennedy AR, Mulvey RE

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2007

Issue: 6

Pages: 598-600

Print publication date: 01/01/2007

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b613655a

DOI: 10.1039/b613655a

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