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High H₂ adsorption by coordination-framework materials

Lookup NU author(s): Dr Xuebo Zhao, Emeritus Professor Mark ThomasORCiD

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Abstract

First-class accommodation: A series of coordination frameworks with different pore sizes (see structure of one; Cu blue, C gray, H white, O red) are prepared from CuII ions and carboxylate ligands of various lengths. Comparison of their sorption properties reveals that smaller pores allow higher densities of adsorbed H2, whereas larger pores allow higher maximum H2 storage capacities. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Publication metadata

Author(s): Lin X, Jia J, Zhao X, Thomas KM, Blake AJ, Walker GS, Champness NR, Hubberstey P, Schroder M

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie - International Edition

Year: 2006

Volume: 45

Issue: 44

Pages: 7358-7364

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - V C H Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.200601991

DOI: 10.1002/anie.200601991

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