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Lookup NU author(s): Emeritus Professor Anthony Harriman
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Shedding new light on the matter: Rather than the conventional approach of utilizing the cascade effect, charge separation can be stabilized in artificial photosynthetic systems simply by the geometry. In these latter systems, light-induced charge separation (CS) in a closely spaced molecular dyad is followed by exceptionally slow charge recombination (CR, see picture) to give a charge-separated state with a lifetime of up to 120 s.
Author(s): Harriman A
Publication type: Review
Publication status: Published
Journal: Angewandte Chemie - International Edition
Year: 2004
Volume: 43
Issue: 38
Pages: 4985-4987
ISSN (print): 1433-7851
ISSN (electronic): 1521-3773
URL: http://dx.doi.org/10.1002/anie.200301762
DOI: 10.1002/anie.200301762
PubMed id: 15317017