Browse by author
Lookup NU author(s): Professor William Clegg, Dr Mark Elsegood
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
The reaction between the bridged bis(imido) complexes {[(CH 2)n(2-C6H4N)2]MoCl 2(dme)} (n=1,2); dme=1,2-dimethoxyethane) and one equivalent of potassium hydridotris(3,5-dimethylpyrazolyl)borate (KTp′) in refluxing thf gives {[(CH2)n(2-C6H4N) 2](Tp′)MoCl} (n=1 (1), n=2 (2)) as red crystalline solids in good yields. Similarly, the reaction between [Mo(NAr)2Cl 2(dme)] or [Mo(NAr)(NBut)Cl2(dme)] (Ar=2,6-Pr2iC6H3) and KTp′ gives green [Tp′Mo(NAr)2Cl] (3) or brown/black [Tp′Mo(NAr)(NBut)Cl] (4), respectively. X-ray crystal structures of the compounds 1, 3 and 4 have been determined. All have octahedral structures with fac coordination for the tridentate Tp′ ligands and near-linear imido groups. © 2003 Elsevier Ltd. All rights reserved.
Author(s): Gibson VC, Redshaw C, Clegg W, Elsegood MRJ, Siemeling U, Turk T
Publication type: Article
Publication status: Published
Journal: Polyhedron
Year: 2004
Volume: 23
Issue: 1
Pages: 189-194
ISSN (print): 0277-5387
ISSN (electronic): 1873-3719
Publisher: Pergamon
URL: http://dx.doi.org/10.1016/j.poly.2003.10.005
DOI: 10.1016/j.poly.2003.10.005
Altmetrics provided by Altmetric
