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Bis(tetraethylammonium) μ-tetrathiomolybdato(VI)-bis[chlorocopper(I)]

Lookup NU author(s): Dr Neil Brooks, Professor William Clegg

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Abstract

The title compound, (Et4N)2[MoS4(CuCl) 2], consists of tetraethylammonium cations of expected geometry, and trinuclear anions in which two opposite edges of an MoS42- tetrahedron are bridged by CuCl units. The bridging of Mo and Cu centres by all four S atoms hardly affects the tetrahedral coordination of Mo and leads to a distorted trigonal planar coordination geometry for Cu, with both chloro ligands terminal. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

Publication metadata

Author(s): Sadr MH, Razmi H, Brooks NR, Clegg W

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2003

Volume: E59

Issue: 12

Pages: m1134-m1136

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1107/S1600536803025807

DOI: 10.1107/S1600536803025807

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