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Lookup NU author(s): Emeritus Professor William McFarlane
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The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cis conformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion of the porphyrin ring is retained in solution.
Author(s): Fujihara T, Rees NH, Umakoshi K, Tachibana J, Sasaki Y, McFarlane W, Imamura T
Publication type: Article
Publication status: Published
Journal: Chemistry Letters
Year: 2000
Volume: 29
Issue: 2
Pages: 102-103
Print publication date: 01/01/2000
ISSN (print): 0366-7022
ISSN (electronic): 1348-0715
Publisher: Chemical Society of Japan
URL: http://dx.doi.org/10.1246/cl.2000.102
DOI: 10.1246/cl.2000.102
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