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Direct bromination of Keggin fragments to give [PW9O28Br6]3-: A polyoxotungstate with a hexabrominated face

Lookup NU author(s): Dr John ErringtonORCiD, Professor William Clegg, Dr Mark Elsegood

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Abstract

Direct halogenations of polyoxometalates [NaPW11O39]6- and [PW9O34]9- led to [PW9O28Br6]3-, a molecular metal oxide with a fully brominated face (see picture). This methodology creates new opportunities for systematic chemistry at polyoxometalate surfaces.

Publication metadata

Author(s): Errington RJ, Wingad RL, Clegg W, Elsegood MRJ

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie - International Edition

Year: 2000

Volume: 39

Issue: 21

Pages: 3884-3886

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co

URL: http://dx.doi.org/10.1002/1521-3773(20001103)39:21<3884::AID-ANIE3884>3.0.CO;2-M

DOI: 10.1002/1521-3773(20001103)39:21<3884::AID-ANIE3884>3.0.CO;2-M

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