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Lookup NU author(s): Dr Geoffrey AbbottORCiD
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Fluorescence has been observed from the exciplex formed between electronically excited 1,4-dicyanonaphthalene and 2,5-dimethyl-2,4-hexadiene in the vapour phase and the kinetics of exciplex formation studied. The enthalphy of vapour-phase exciplex formation in this pair of molecules was found to be 8 kJ mol–1 and activation energies for formation and reverse dissociation of the exciplex were found to be 15 and 23 kJ mol–1, respectively.
Author(s): Abbott GD, O'Connor DV, Phillips D
Publication type: Article
Publication status: Published
Journal: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Year: 1981
Volume: 77
Issue: 6
Pages: 1381-1392
ISSN (print): 0300-9599
ISSN (electronic): 1463-9084
URL: http://dx.doi.org/10.1039/f19817701381
DOI: 10.1039/f19817701381
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