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Lookup NU author(s): Professor Judith Howard, Professor Mike ProbertORCiD
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© 2018 The coordination properties of the 2-aryl-1,3,2-dioxaphospholane 2,6-(CF3)2C6H3P(OCH2)2 1 (L) have been investigated, by reaction with elemental selenium in solution to form the phosphorus(V) oxidation product 2,6-(CF3)2C6H3P(Se)(OCH2)2 2, and with metal-containing precursors to form three new complexes trans-[PdCl(μ-Cl)(L)]2 3, cis-[PdMe2L2] 4 and [AuCl(L)] 5. All of the metal complexes have been characterised by single-crystal X-ray structure determination.
Author(s): Coffer PK, Dillon KB, Howard JAK, Probert MR, Shepherd HJ
Publication type: Article
Publication status: Published
Journal: Inorganica Chimica Acta
Year: 2018
Volume: 479
Pages: 24-29
Print publication date: 01/07/2018
Online publication date: 20/04/2018
Acceptance date: 18/04/2018
ISSN (print): 0020-1693
ISSN (electronic): 1873-3255
Publisher: Elsevier BV
URL: https://doi.org/10.1016/j.ica.2018.04.030
DOI: 10.1016/j.ica.2018.04.030
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