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Lookup NU author(s): Professor Richard Henderson
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Rates of proton transfers between lutH(+) (lut = 2,6-dimethyl-pyridine) and [Ni(XPh)(PhP{CH2CH2PPh2}(2))](+) (X = O, S or Se) are slow and show little variation (k(O) :k(S) :k(Se) = 1:12:9). This unusual behaviour is a consequence of sterics affecting the optimal interaction between the reactants prior to proton transfer.
Author(s): Aiwaaly A, Henderson RA
Publication type: Article
Publication status: Published
Journal: Chemical Communications
Year: 2014
Volume: 50
Issue: 68
Pages: 9669-9671
Print publication date: 04/09/2014
Online publication date: 04/07/2014
Acceptance date: 04/07/2014
ISSN (print): 1359-7345
ISSN (electronic): 1364-548X
Publisher: Royal Society of Chemistry
URL: http://dx.doi.org/10.1039/c4cc04197f
DOI: 10.1039/c4cc04197f
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