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Lookup NU author(s): Emeritus Professor Mark ThomasORCiD
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Porous NOTT-202a shows exceptionally high uptake of SO2, 13.6 mmol g(-1) (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO2 uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong pi...pi interactions between interpenetrated networks.
Author(s): Yang SH, Liu LF, Sun JL, Thomas KM, Davies AJ, George MW, Blake AJ, Hill AH, Fitch AN, Tang CC, Schroder M
Publication type: Article
Publication status: Published
Journal: Journal of the American Chemical Society
Year: 2013
Volume: 135
Issue: 13
Pages: 4954-4957
Print publication date: 13/03/2013
ISSN (print): 0002-7863
ISSN (electronic): 1520-5126
Publisher: American Chemical Society
URL: http://dx.doi.org/10.1021/ja401061m
DOI: 10.1021/ja401061m
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