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Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

Lookup NU author(s): Professor William Clegg, Dr Luca Russo

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Abstract

The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).

Publication metadata

Author(s): Baillie SE, Clegg W, Garcia-Alvarez P, Hevia E, Kennedy AR, Klett J, Russo L

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2011

Volume: 47

Issue: 1

Pages: 388-390

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/c0cc02164d

DOI: 10.1039/c0cc02164d

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