Toggle Main Menu Toggle Search

Open Access padlockePrints

Synthesis and crystal structures of bis(N-phenyl-3,5-dinitrothiobenzamidato)mercury(II) and bis(N-phenyl-4-nitrothiobenzamidato)mercury(II)

Lookup NU author(s): Professor Mohammad Habibi, Dr Neil Brooks, Professor William Clegg

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

The crystal structures of bis(N-phenyl-3,5-dinitrothiobenzamidato)mercury(II) (1) and bis(N-phenyl-4-nitrothiobenzamidato)mercury(II) (2) have been determined by single-crystal X-ray diffraction. Both the complexes crystallize in centrosymmetric monoclinic space groups with crystallographic inversion symmetry. The S-Hg-S linkage is thus precisely linear in each case. Significant secondary interactions include intramolecular Φ coordination by phenyl groups, aromatic ring stacking in the case of 1 only, and a number of intramolecular and intermolecular C-H...X contacts (X=O, N, S) influencing the molecular conformation and crystal packing. © 2010 Taylor & Francis.


Publication metadata

Author(s): Habibi M, Tangestaninejad S, Fallah-Shojaei A, Barati K, Brooks N, Clegg W

Publication type: Article

Publication status: Published

Journal: Journal of Coordination Chemistry

Year: 2010

Volume: 63

Issue: 4

Pages: 579-585

Print publication date: 01/02/2010

ISSN (print): 0095-8972

ISSN (electronic): 1026-7441

Publisher: Taylor & Francis Ltd.

URL: http://dx.doi.org/10.1080/00958970903556096

DOI: 10.1080/00958970903556096


Altmetrics

Altmetrics provided by Altmetric


Share